2,7-Dimethoxy-1-(4-nitrobenzoyl)-naphthalene
نویسندگان
چکیده
In the title compound, C(19)H(15)NO(5), the dihedral angle between the naphthalene ring system and the benzene ring is 61.97 (5)°. The dihedral between the naphthalene ring system and the bridging carbonyl C-C(=O)-C plane is 54.68 (6)°, far larger than that [12.54 (7)°] between the phenyl group and the bridging carbonyl group. The nitro group and the phenyl ring are almost coplanar [O-N-C-C torsion angle = 2.94 (19)°]. In the crystal, mol-ecules are linked by C-H⋯π inter-actions and the phenyl rings are involved in a centrosymmetric π-π inter-action with a perpendicular distance of 3.523 Å and a lateral offset of 1.497 Å. In addition, weak inter-molecular C-H⋯O hydrogen bonds are formed between an H atom of one meth-oxy group and a nearby carbonyl O atom.
منابع مشابه
Crystal structure of 2,7-diethoxy-1,8-bis(4-nitrobenzoyl)naphthalene
The title compound, C28H22N2O8, possesses crystallographically imposed twofold symmetry, with the two central carbon atoms of the naphthalene unit lying on the rotation axis. The two benzoyl groups in the mol-ecule are twisted away from the attached naphthalene unit with a C-C-C=O torsion angle of 49.05 (15)° between the naphthalene unit and the carbonyl group. The dihedral angle between the na...
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In the title compound, C36H28O4, the 1-naphthoyl groups at the 1- and 8-positions of the central 2,7-dieth-oxy-naphthalene ring system are aligned almost anti-parallel and make a dihedral angle of 76.59 (4)°. The dihedral angles between the central 2,7-dieth-oxy-naphthalene ring system and the terminal naphthalene ring systems are 86.48 (4) and 83.97 (4)°. In the crystal, C-H⋯π inter-actions be...
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In the title mol-ecule, C(23)H(18)O(3), the dihedral angle between the two naphthalene ring systems is 80.44 (4)°. The mean plane of the bridging carbonyl C-C(=O)-C group makes a torsion angle of -68.55 (17)° with the naphthalene system of the 2,7-dimeth-oxy-naphthalene unit and a torsion angle of -9.01 (19)° with the naphthalene ring system of the naphthoyl group. In the crystal, a weak C-H⋯O ...
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In the macrocyclic title compound, C(26)H(12)Cl(2)N(6)O(4), an O-atom-bridged calix[2]naphthalene-[2]triazine synthesized using a one-pot approach from naphthalene-2,7-diol and cyanuric chloride, the two isolated naphthalene planes and the two triazine-2,6-di-oxy planes adopt a 1,3-alternate configuration, with a dihedral angle of 84.10 (8)° between the naphthalene rings and a dihedral angle of...
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